Author's posts

Pique the Geek 20120902: Why we do not burst into flame — Oxygen

Oxygen is one of the most fascinating elements for many reasons.  Before we get to it, I first want to point out that the column of the periodic table that starts with nitrogen are called pnictogens, whislt the column starting with oxygen are called chalcogens.  The term pnictogen is recent, dating form the 1950s.  It comes from the Greek plural noun pnikta which means something on the order of “those that are suffocated” in reference to the fact that nitrogen will not support life.  The “gen” part is from the Greek gonos, “born” or “generated”.

Chalcogen comes from the ancient Greek chalkos, meaning “ore” and gonos, and in fact an extremely large number of metal ores contain oxygen or sulfur of both.  Selenium and tellurium are chalcogens that are often found in gold and silver ores.

Time before last we discussed nitrogen and molecular orbital diagrams for it.  If you are not hip to MO diagrams, I suggest you read that part of the link before you try to tackle the MO diagrams for oxygen.

My Little Town 20120828: Dad’s Garden

Sorry to post late, but I got an emergency call from next door because The Little Girl had lost her bottle and The Girl was trying to get her to the bed so that she (The Girl) and I could visit.  I hope that everyone understands that important personal interactions are more important than blogging.  The Girl found her bottle, in an area that I suggested.  She and I make a good team.

Those of you that read this regular series know that I am from Hackett, Arkansas, just a mile or so from the Oklahoma border, and just about 10 miles south of the Arkansas River.  It was a rural sort of place that did not particularly appreciate education, and just zoom onto my previous posts to understand a bit about it.

I have written about Dad gardening before, so I hope that these are new stories.  I think that at least most of them will be.  Dad did not garden as long as my grandmum did, but when she got too feeble to garden effectively Dad, who was retired by then, took over the chore.

Dad did not do things an a small way.  He just about tripled the area that Ma gardened and moved the garden from the north side of the driveway to the south because there was more room.  He bought a rear tine tiller from the former Mrs. Translator’s father and broke the entire space with it.

Pique the Geek 20120826: Nitrogen, Extremely Versatile

Last time we talked about the unusual properties of elemental nitrogen mostly and how stable it is.  We only touched on a little of the fascinating and extremely complex chemistry of nitrogen, ONCE we can get it in a form other than the incredibly stable elemental form.

This time we shall remedy this, although entire graduate level texts have been written on the subject.  Tonight we shall take a brief survey of the impact that nitrogen has on living organisms, industry, and a few other areas.  We shall attempt to do this by looking at various oxidation states, and nitrogen has more than any other element.

The basic concept is that atoms can either donate or accept electrons from other atoms.  When an atom donates electrons, it is oxidized, and when it accepts electrons it is reduced.  Thus, chlorine bleach works because hypochlorite ion is a strong oxidizing agent and breaks up large, colored molecules to smaller, colorless ones.

Popular Culture 20120824: Jethro Tull — Aqualung

Aqualung is the forth album by Tull and many people think that it is their best.  I favor Thick as a Brick, but it is still an excellent album.  Rumor has it that critical comments about Aqualung spawned Thick as a Brick, and we shall discuss that in a bit.

It was released on 19710319 on Island Records in the UK and Reprise in the US.  By this time Anderson had completely taken control of the band, and all of the songs are written by him except for the title track which was cowritten by his wife at the time, Jennie.  Anderson, along with Terry Ellis, produced it.

The band lineup was different than that of Benefit, with Jeffrey Hammond replacing replacing Glen Cornick on bass and Barriemore Barlow replacing Clive Bunker on drums.  Remember, Jethro Tull has had more personnel changes than many bands.  Otherwise the lineup was the same as on Benefit.

My Little Town 20120822: Dad and The Lawn

I took a week off from blogging last week for a number of reasons.  One was that I was having trouble getting my mind around topics.  Another was being in sort of a strange set of moods that have made concentration rather difficult.  Yet again, and probably the root cause of the other two is either spending large amounts of time with someone (no time to write) or no time at all (no motivation to write).  In any event, I think that I have some balance back.

Those of you that read this regular series know that I am from Hackett, Arkansas, just a mile or so from the Oklahoma border, and just about 10 miles south of the Arkansas River.  It was a rural sort of place that did not particularly appreciate education, and just zoom onto my previous posts to understand a bit about it.

Dad was sort of obsessive about the lawn.  We had a big yard, the front being the largest and the back second, with the sides being somewhat smaller but still large by most standards.  The problem was that we had lots of large trees.  In the front were two post oaks, a hackberry (that was hollow at the bottom), a mockernut hickory (one with really sweet nuts, unlike many mockernuts), and a papershell pecan.

The side on the south had a walnut tree that I planted, and the back had two large walnut trees.  The side on the north had a very tall pine and a redbud tree.  All of that shade made it sort of hard to grow grass.

Pique the Geek 20120819: Nitrogen, without Life?

I took a week off from blogging last week for a number of reasons.  One was that I was having trouble getting my mind around topics.  Another was being in sort of a strange set of moods that have made concentration rather difficult.  Yet again, and probably the root cause of the other two is either spending large amounts of time with someone (no time to write) or no time at all (no motivation to write).  In any event, I think that I have some balance back.

I got tired of writing about carbon so we shall move on to nitrogen.  With an atomic number (Z) of 7, it is the element after carbon.  Nitrogen is another of the few elements that ordinary people encounter on a daily basis, because it comprises around 78% of the atmosphere of the earth.

There are two stable isotopes of nitrogen, the very common 14N (99.64%), the rest being 15N.  Both of these isotopes are formed in larger stars by stellar nucleosynthesis.  Nitrogen is peculiar in that it is one of only five nucleides that are stable with both an odd number of protons and neutrons.  It is really unusual in that 14N is by far the most common isotope of nitrogen.

Popular Culture 20120810: Jethro Tull, the Beginning

One of the most complicated bands in many ways is the British band Jethro Tull.  They are complicated in their music, extremely complicated in their personnel, and almost mind bogglingly complicated in insofar as why I adore a limited set of their work and either care not a fig or actually dislike the rest.  I have such a love/hate relationship for any other band.

I do not understand why I feel this way, but I do.  At their best, they are superb.  When they are a bit off they are still better than most bands, but the material that I dislike is just awful, at least in my view.

This is why it has taken me so long to get started with this series.  I generally try to write about things that I have unambiguous feelings, usually bands that I really like.  Sometimes I write about horrible acts, like Ray Stevens, who really never did anything of real merit.  But to write about a band that can move me greatly with some material and with other material make me say, “What IS that?” is quite different.  Please bear with me!

My Little Town 20120808: The Forbes Dynasty

Those of you that read this regular series know that I am from Hackett, Arkansas, just a mile or so from the Oklahoma border, and just about 10 miles south of the Arkansas River.  It was a rural sort of place that did not particularly appreciate education, and just zoom onto my previous posts to understand a bit about it.

From the 1880s to the Great Depression Hackett was a booming town.  Coal drove the economy, but there was significant agriculture as well.  Coal was king, though.  Hackett coal is ideal for making coke, basically the coal counterpart of charcoal.  Coke was and still is used in enormous quantities to produce steel, and during The Gilded Age the steel mills were running at capacity.

Not just any coal will make suitable coke.  The particular kind of bituminous coal found at Hackett is ideal for coking and hundreds of men mined it there.  There were rail lines to carry it away and it found its way up north to the steel mills.

Pique the Geek 20120805: Yet More Carbon

Last time we finished our discussion of diamond, and now we move to what is pretty incorrectly called amorphous carbon.  Truly amorphous materials. like glass, have no true crystal structure (although there may be some local microstructures) that repeats regularly.

When used in the sense of carbon, only recently produced thin films of carbon are truly amorphous.  These are of research interest for the most part, although I would be quite surprised if practical uses are not found for them before long.

We shall discuss forms of carbon traditionally called amorphous even though they are not truly amorphous.  These include some of the most commonly encountered forms of carbon, and almost everyone has seen and touched at least a few examples.

Popular Culture 20120803: Leroy Jethro Gibbs

NCIS is really a good TeeVee program.  The writing is realistic, the characters well developed, and the mysteries usually pretty good, often with last minute twists.  Of all of the characters, Gibbs (played with aplomb by Mark Harmon) is by far the most complex.

This piece is not intended to be a history of the show, but rather my take on the personality of the character.  Various scenes that I remember may be used to illustrate my points, but once again this is more of a character analysis of Gibbs than a narrative of the program.

First and foremost, Gibbs is damaged goods.  He was always in trouble when he was a kid, often rescued by his father, Jackson (played by the wonderful Ralph Waite).  Some of these incidents are told in flashback, and the young Gibbs is played by Sean Harmon, Mark Harmon’s son by Pam Dawber.

My Little Town 20120801: The Gang

Those of you that read this regular series know that I am from Hackett, Arkansas, just a mile or so from the Oklahoma border, and just about 10 miles south of the Arkansas River.  It was a rural sort of place that did not particularly appreciate education, and just zoom onto my previous posts to understand a bit about it.

My maternal grandmum married John Mackey, a really nice man who had been a doughboy during World War I.  She had been widowed for many years (my grandfather died years before I was born) and John had been married briefly decades before, so he was essentially a bachelor.

John had a little candy store on Main Street in Hackett where he sold candy, cold soft drinks, flashlight batteries, and sundries.  He never made any money with the store because he gave so much stuff away to kids (like me).  He lived in the back of the store until he married my grandmum.  He had a little pension for serving in World War I and also a black lung pension for being a coal miner for years.

The store was the gathering place for the old men in town.  He had an awning over the storefront and several benches and chairs under it.  He also had chairs and tables inside for winter and he had a pot bellied coal stove in the store.  At the time coal was readily available for the consumer market in Hackett.

Pique the Geek 20120729: Carbon Copy

Last time we started talking about the allotropes of carbon, finished graphite and began with diamond.  Tonight we shall continue the diamond saga and maybe move to a third common allotrope.

Last week I was having some connectivity problems and, quite frankly, was ill with a bad cold, so I just did not feel much like writing.  I am better (much) this week and my computer seems to be functioning within design parameters.

Since the part that I wrote about diamond was so short last time, I shall paraphrase it as the start of this piece.  That way you do not have to hit the link to get up to speed.

Load more